Electrode Potential and Electrochemical – 1

quarant9

Electrode Potential and Electrochemical – 1

  1. The equation representing the process by which standard reduction potential of zinc can be defined is
    1. Zn2+ (S) + 2e ——> Zn
    2. Zn (g) ——> Zn2+ (g) + 2e
    3. Zn2+ (g) + 2e ——> Zn
    4. Zn2+ (aq.) + 2e ——> Zn (S)

  2. The cell emf depends on
    1. Size of anode
    2. Volume of solution
    3. Temperature
    4. All of them

  3. Emf of a cell in terms of the reduction potential of its left and right electrodes is
    1. E = ELeft – ERight
    2. E = ELeft + ERight
    3. E = ERight – ELeft
    4. E = ERight + ELeft

  4. EO values of Mg2+ | Mg, Fe2+| Fe and Zn2+ | Zn are -2.37V, -0.44V and -0.76V respectively. The correct statement is
    1. Mg oxidises Fe
    2. Zn oxidises Fe
    3. Zn reduces Mg2+
    4. Zn reduces Fe2+

  5. Which one of the following is the wrong statement about electrochemical series?
    1. Active Metals have a negative reduction potential
    2. Active non-metals have positive reduction potentials
    3. Metals above hydrogen liberate hydrogen from acids
    4. Metals below hydrogen are strong reducing agents

  6. Strongest Reducing agent is
    1. K
    2. Mg
    3. Al
    4. I

  7. The standard reduction potential at 25°C for the following half-reaction are given against each
    Zn2+ (aq) + 2e ——> Zn(s), – 0.762
    Cr3+ (aq) + 3e ——> Cr(s), – 0.740
    2H+ + 2e ——> H2 (g), 0.00
    Fe3+ + 2e ——> Fe2+, – 0.77
    Which is the strongest reducing agent?
    1. Zn
    2. Cr
    3. H2 (g)
    4. Fe2+ (aq)

  8. Red hot carbon will remove oxygen from the oxide XO and YO but not from ZO. Y will remove oxygen from XO. Use this evidence to deduce the order of activity of the three metals X, Y and Z putting the most active first
    1. XYZ
    2. ZYX
    3. YXZ
    4. ZXY

  9. Which of the following metals does not give the following reaction?
    M + water ——–> oxide or hydroxide + H2
    1. Iron
    2. Sodium
    3. Mercury
    4. Magnesium

  10. Which is the best reducing agent?
    1. F-1
    2. Cl-1
    3. Br-1
    4. I

  11. If a spoon of copper metal is placed in a solution of ferrous sulphate
    1. Cu will precipitate out
    2. Iron will precipitate
    3. Cu and Fe will precipitate
    4. No reaction will take place

  12. Which one will liberate Br2 from KBr
    1. HI
    2. I2
    3. Cl2
    4. SO2

  13. Using the standard electrode potential values given below, decide which of the statements I, II, III, IV are correct. Choose the right answer
    Fe2+ + 2e Fe(s); EO = -0.44 V
    Cu2+ + 2e Cu(s); EO = +0.34 V
    Ag+ + e Ag(s); EO = +0.80 V
    I. Copper can displace from FeSO4 solution.
    II. Iron can displace copper from CuSO4 solution
    III. Silver can displace copper from CuSO4 solution
    IV. Iron can displace silver from AgNO3 solution
    1. I and II
    2. II and III
    3. II and IV
    4. I and IV

  14. The standard electrode potential value of the elements A, B and C are 0.68, -2.50 and 0.50 V respectively. The order of their reducing power is
    1. A > B > C
    2. A > C > B
    3. C > B > A
    4. B > C > A

  15. Zn can not displace following irons from their aqueous solution
    1. Ag+
    2. Cu2+
    3. Fe2+
    4. Na+

  16. When a piece of sodium metal is dropped in the water a reaction takes to yield hydrogen because
    1. Sodium loses electrons
    2. Sodium acts as an oxidising agent
    3. Water loses electrons
    4. Water acts as a reducing agent

  17. The reduction potential values are given below:
    Al3+ / Al = 1.67 volt
    Mg2+ / Mg = -2.34 volt
    Cu2+ / Cu = +0.34 volt
    I2 / 2I = +0.53 volt
    Which one is the best reducing agent:
    1. Al
    2. Mg
    3. Cu
    4. I2

  18. From the values given below:
    Al3+ / Al = 1.67 volt
    Mg2+ / Mg = -2.34 volt
    Cu2+ / Cu = +0.34 volt
    I2 / 2I = +0.53 volt
    Which one is the best oxidising agent:
    1. Al
    2. Mg
    3. I2
    4. Cu

  19. The standard electrode potential of four elements A, B, C and D are -3.05, 1.66, -0.40 and 0.80 volts. The highest chemical activity will be shown by
    1. A
    2. B
    3. C
    4. D

  20. The standard reduction potential at 25°C of Li+/Li, Ba2+/Ba, Na+/Na and Mg2+/Mg are -3.05, -2.73, -2.71 and 2.37 volt respectively. Which one of the following is the strongest oxidising agent
    1. Na+
    2. Li+
    3. Ba2+
    4. Mg2+

Answers:

  1. 4
  2. 3
  3. 3
  4. 4
  5. 4
  6. 1
  7. 4
  8. 2
  9. 3
  10. 4
  11. 4
  12. 3
  13. 3
  14. 4
  15. 4
  16. 1
  17. 2
  18. 3
  19. 1
  20. 4
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